The country couple scored a big hit with the Bee Gees tune over three decades ago and they teamed up again to close the three-hour fundraiser for the victims of the Tennessee wildfires in Nashville.
Dolly also kicked off the evening by performing an emotional rendition of My Mountains, My Home, while Chris Stapleton, Don McLean, Reba McEntire, Chris Young, and Montgomery Gentry also sang as the donations poured in.
There were also special pleas for cash from Miley Cyrus and Kiefer Sutherland, and big cash handouts from Kid Rock, Taylor Swift, Kenny Chesney and Paul Simon, who called in to chat to Dolly Parton and offered up $100,000 (£79,000).
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